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Potassium tetrachloroplatinate
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Potassium tetrachloroplatinate : ウィキペディア英語版
Potassium tetrachloroplatinate

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Potassium tetrachloroplatinate(II) is the chemical compound with the formula K2PtCl4. This reddish orange salt is an important reagent for the preparation of other coordination complexes of platinum. It consists of potassium cations and the square planar dianion PtCl42−. Related salts are also known including Na2PtCl4, which is brown-colored and soluble in alcohols, and quaternary ammonium salts, which are soluble in a broader range of organic solvents.
== Preparation ==
Potassium tetrachloroplatinate is prepared by reduction of the corresponding hexachloroplatinate salt with hydrazine. K2PtCl4 is one of the salts that is most easily obtained from platinum ores. The complex is appreciably soluble only in water. Treatment with alcohols, especially in the presence of base, causes reduction to platinum metal. Conversion to organic salts, such as ()2PtCl4 are soluble in chlorocarbons.

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